名称：叔-丁基 (1r,2r,4s)-rel-2-氨基-7-氮杂二环[2.2.1]庚烷-7-甲酸基酯
英文名称：tert-butyl endo-2-amino-7-azabicyclo[2.2.1]heptane-7-carboxylate
分子式：c11h20n2o2
分子量: 212.29
cas no.：1000870-15-4
结构式：
规格：97%
用途：基础原料、有机中间体、医药中间体
合成路线如下：
pearlman's catalist; hydrogen; methanol;
reactants can be synthesized in 4 steps.
tetrahedron, vol. 68, 4, (2012), p. 1286 - 1298 general procedure: palladium hydroxide on carbon (20 wt percent, 100 mg) was added to a solution of azide 22 or 34 (5 mmol) in methanol (15 ml), the mixture was stirred under hydrogen at room temperat ure overnight, filtered through celite and evaporated. the residue was chromatographed on silica gel (100 g) in ethyl acetate/1,4-dioxane/ethanol/water/concd aqueous ammonia (18:3:2:1:1).